Entropy, Enthalpy, and Side Arm Porphyrins. 1. Thermodynamics of Axial Ligand Competition between 3-Picoline and a Series of 3-Pyridyl Ligands Covalently Attached to Zinc Tetraphenylporphyrin

DOI: 10.1021/ja00537a019

Source and publish data:

Journal of the American Chemical Society p. 5530 - 5538 (1980)

Update date:2022-07-31

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Authors:

Walker, F. Ann

Benson, Mabry

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Article abstract of DOI:10.1021/ja00537a019

A series of five-coordinate zinc tetraphenylporphyrins, each with a covalently attached 3-pyridyl side chain of different length, were synthesized.NMR spectroscopy was used to study the displacement of the 3-pyridyl ligand by free 3-picoline in toluene-d<

Full text of DOI:10.1021/ja00537a019

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