Journal of the American Chemical Society
Communication
(16) Murakami reported the asymmetric addition to but-2-ene-1,4-
diol, which gives an olefinic product resulting from β-hydroxy
elimination, see: Miura, T.; Takahashi, Y.; Murakami, M. Chem.
Commun. 2007, 595.
AUTHOR INFORMATION
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Corresponding Author
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Notes
The authors declare no competing financial interest.
ACKNOWLEDGMENTS
■
Financial support from Institute of Materials Research and
Engineering is gratefully acknowledged.
REFERENCES
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̈
̈
(24) For a 1,4-Rh shift from an alkylrhodium intermediate to an
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(25) For example, retention of configuration at protonolysis has been
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(26) The relative reaction rate was obtained by multiple sets of the
reactions stopped at low conversions (12−50% yield, 5−15 min).
(27) (a) Scott, V. J.; Labinger, J. A.; Bercaw, J. E. Organometallics 2011,
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(29) Simple internal olefins (2-octene, cyclohexene) did not undergo
the hydrophenylation under the conditions of Table 1, entry 6.
(15) Lautens also reported an asymmetric hydroarylation scheme in
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