
Journal of the Chemical Society. Chemical communications p. 566 - 567 (1992)
Update date:2022-07-30
Topics:
Eberson, Lennart
Hartshorn, Michael P.
Radner, Finn
Robinson, Ward T.
By the isolation and kinetic studies of an adduct (cis-1,4-dihydro-1-nitro-4-trinitromethylnaphthalene) from the photolysis of naphthalene-tetranitromethane in dichloromethane or acetonitrile, it is shown that the route to nitro substitution products proceeds via addition-elimination, the latter step being either thermal or base-catalysed.
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