Synlett p. 1415 - 1419 (2013)
Update date:2022-08-04
Topics:
Kumar, Harish
Reddy, A. Srinivas
Yadav
Reddy, B. V. Subba
A flexible and highly diastereoselective formal synthesis of hapalosin, a cyclodepsipeptide isolated from the blue green alga Hapalosiphon welwitschii and having multidrug-resistance-reversing activity is described. The synthetic route involves the addition of organometallic reagent to N-tert- butanesulfinylimine, Jung nonaldol aldol reaction, and Yamaguchi esterification as key steps. Georg Thieme Verlag Stuttgart · New York.
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Doi:10.1016/S0277-5387(00)83689-X
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