Metal-free borane-catalyzed highly stereoselective hydrogenation of pyridines

DOI: 10.1021/ja406761j

Source and publish data:

Journal of the American Chemical Society p. 12968 - 12971 (2013)

Update date:2022-09-26

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Authors:

Liu, Yongbing

Du, Haifeng

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Article abstract of DOI:10.1021/ja406761j

A metal-free direct hydrogenation of pyridines was successfully realized by using homogeneous borane catalysts generated from alkenes and HB(C ₆F₅)₂ via in situ hydroboration. The reaction affords a broad range of piperidines in high yields with excellent cis stereoselectivities.

Full text of DOI:10.1021/ja406761j

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