Palladium-catalyzed reaction between aryl or alkenyl halides and (1-carbalkoxy-1-alkenyl)zinc iodides. A new class of unmasked β-substituted acrylate α-anion equivalents

DOI: 10.1016/0022-328X(93)83005-G

Source and publish data:

Journal of Organometallic Chemistry p. 33 - 43 (1993)

Update date:2022-08-03

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Authors:

Rossi, Renzo

Carpita, Adriano

Bellina, Fabio

Cossi, Paolo

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Article abstract of DOI:10.1016/0022-328X(93)83005-G

Unmasked β-substituted acrylate α-anion equivalents have been directly and very efficiently prepared by insertion of zinc metal into the carbon-iodine bonds of alkyl (E)- or (Z)-2-iodo-2-alkenoates, (E)- or (Z)-(4), respectively.The stereoisomeric composi

Full text of DOI:10.1016/0022-328X(93)83005-G

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