Tetrahedron Letters p. 6169 - 6172 (1992)
Update date:2022-08-02
Topics:
Dang, Hai-Shan
Roberts, Brian P.
In the presence of an amine-borane polarity reversal catalyst, vinyl epoxides react at the α-C-H group of an ester to give allylic alcohols.A free radiacal chain mechanism is followed, involving ring opening of an intermediate oxiranylcarbinyl radical to
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