A New Rhodium(II) Phosphate Catalyst for Diazocarbonyl Reactions Including Asymmetric Synthesis

DOI: 10.1016/S0040-4039(00)61106-1

Source and publish data:

Tetrahedron Letters p. 5983 - 5986 (1992)

Update date:2022-08-05

Topics:

Authors:

McCarthy, Noreen

McKervey, M. Anthony

Ye, Tao Ye, Tao

McCann, Malachy

Murphy, Eamonn

Doyle, Michael P.

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Article abstract of DOI:10.1016/S0040-4039(00)61106-1

A new homochiral Rh(II) complex, Rh2<(+)-phos>2*5H2O, where (+)phosH represents (S)-(+)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate, has been prepared and used as a catalyst for reactions of diazocarbonyl compounds leading to enantioselective 2,3-s

Full text of DOI:10.1016/S0040-4039(00)61106-1

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