A New Rhodium(II) Phosphate Catalyst for Diazocarbonyl Reactions Including Asymmetric Synthesis

Article abstract of DOI:10.1016/S0040-4039(00)61106-1

A new homochiral Rh(II) complex, Rh2<(+)-phos>2*5H2O, where (+)phosH represents (S)-(+)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate, has been prepared and used as a catalyst for reactions of diazocarbonyl compounds leading to enantioselective 2,3-s