Journal of the Chemical Society. Perkin transactions I p. 3019 - 3022 (1992)
Update date:2022-08-03
Topics:
Gordon, John F.
Hanson, James R.
Jarvis, Andrew G.
Ratcliffe, Arnold H.
The preparation of the 3α,18-monoacetonide of aphidicolin and its selective oxidation at C-17, is described.Catalytic oxidation of aphidicolin affords 16β-hydroxy-3-oxo-19-noraphidicolan-17-oic acid.The conversion of this into 19-noraphidicolan-16β-ol and its biotransformation by the fungus, Cephalosporium aphidicola, to a 19-noraphidicolin, is reported.
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