Radical Cyclisation Reactions Leading to Polyhydroxylated Cyclopentane Derivatives: Synthesis of (1R,2R,3S,4R)- and (1S,2S,3R,4S)-4-Hydroxyethylcyclopentane-1,2,3-triol

DOI: 10.1039/P19920002625

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 2625 - 2632 (1992)

Update date:2022-08-04

Topics: Synthesis

Authors:

Roberts, Stanley M.

Shoberu, Karoline A.

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Article abstract of DOI:10.1039/P19920002625

The tetrol (-)-1 has been prepared from a derivative of (D)-allose 3.The stereoselective carbocyclization reaction (8->11) formed the key step in this sequence.The enantiomeric cyclopentane derivative (+)-1 was also prepared from compound 3.In this synthe

Full text of DOI:10.1039/P19920002625

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