Building blocks for the synthesis of glycosyl-myo-inositols involved in the insulin intracellular signalling process

Article abstract of DOI:10.1016/0008-6215(92)85041-W

Glycosylation of (+/-)-1-O-benzyl-2,3:5,6-di-O-isopropylidene-myo-inositol (4) with 6-O-acetyl-4-O-allyl-2-azido-3-O-benzyl-2-deoxy-β-D-glucopyranosyl trichloroacetimidate (6) gave the 4-O-(2-amino-2-deoxy-α-D-glucopyranosyl)-myo-inositol derivative (9) a