A General Route to N(SCl)2+ and SNS+ Salts

DOI: 10.1039/DT9920003097

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3097 - 3104 (1992)

Update date:2022-08-02

Topics: Crystallization Synthetic route Nucleophilic substitution Nuclear Magnetic Resonance (NMR) Reaction Mechanism Electrophilic Substitution

Authors:

Ayres, Bryan

Banister, Arthur J.

Coates, Philip D.

Hansford, Michael I.

Rawson, Jeremy M.

et al. et al.

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Article abstract of DOI:10.1039/DT9920003097

A 1:3 mixture of (NSCl)3 and AgX (where X is a 'hard' anion) in liquid SO2 act as a convenient soure of X.The reactivity of salts of this SN⁺ cation towards sulfur and SCl2 has been examined.Reaction of (NSCl)3 with AgX (X = AsF6, SbF6 or C

Full text of DOI:10.1039/DT9920003097

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