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3-Methylenetetrahydrofurans and 3-Methylenepyrrolidines by Addition of 2-(Bromozincmethyl)-2-alkenyl Ethers or 2-(Chloromagnesiomethyl)-2-alkenyl Ethers to Aldehydes, Ketones and Imines followed by Pd(0)-Catalyzed Cyclization

DOI: 10.1016/S0040-4020(01)92280-X

Source and publish data:

Tetrahedron p. 9877 - 9900 (1992)

Update date:2022-08-05

Topics:

Authors:

Louw, Jaap van derLouw, Jaap van der

Baan, Juul L. van derBaan, Juul L. van der

Stichter, HenkStichter, Henk

Out, Gerardus J. J.Out, Gerardus J. J.

Kanter, Franciscus J. J. deKanter, Franciscus J. J. de

et al.et al.

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Article abstract of DOI:10.1016/S0040-4020(01)92280-X

Reaction of 2-(bromozincmethyl)-2-alkenyl ethers 1 or 2-(chloromagnesiomethyl)-2-alkenyl ethers 2 with aldehydes, ketones and imines affords the addition products 4 and 8, which undergo Pd(0)-catalyzed cyclization to the 3-methylenetetrahydrofurans 6 (R View More

Full text of DOI:10.1016/S0040-4020(01)92280-X

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