Tetrahedron p. 10563 - 10568 (1992)
Update date:2022-08-04
Topics:
Rukachaisirikul, Vatcharin
Hoffmann, Reinhard W.
Ketones are generated by photolysis (>320 nm) of 6-phenanthridinylmethyl ethers of secondary alcohols.The 6-phenanthridinylmethyl group may therefore be utilized as a latent carbonyl function, especially as the 6-phenanthridinyl-methyl group is chemically inert toward hydroboration, Grignard additions, LiAlH4-reduction, bromination or ozonolysis at other parts of the molecule.
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