Journal of the Chemical Society. Perkin transactions II p. 1915 - 1918 (1983)
Update date:2022-08-04
Topics:
Funabiki, Takuzo
Yamazaki, Yasuyuki
Sato, Yoshihiro
Yoshida, Satohiro
Acetylenes are regioselectively hydrocyanated by cyanocobaltate prepared at CN:Co < 5:1 to give saturated secondary nitriles via unsaturated nitriles without the use of hydrogen cyanide, and partly hydrogenated to olefins or saturated hydrocarbons.In the presence of 2,2'-bipyridyl, hydrogenation of acetylene predominates, reflecting the formation of a highly active hydride complex
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