A Novel Rearrangement in the Sterically Congested (2,4,6-Cycloheptatrienyl)(phenylsulfinyl)methyl Group

DOI: 10.1246/cl.1992.2393

Source and publish data:

Chemistry Letters p. 2393 - 2396 (1992)

Update date:2022-08-04

Topics:

Authors:

Sugihara, Yoshikazu

Kanemaru, Jun-ichi

Saito, Junji

Murata, Ichiro

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Article abstract of DOI:10.1246/cl.1992.2393

An oxidation product of 3-bromo-1-formyl-4-<(2,4,6-cycloheptatrienyl)(phenylthio)methyl>azulene with m-chloroperbenzoic acid was transformed into 3-bromo-1-formyl-4-(E)-styrylazulene upon standing at 0 deg C in a solid state.A similar rearrangement was al

Full text of DOI:10.1246/cl.1992.2393

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