Synthesis of (-)-Talaromycin A. The use of the Δ2 effect for stereocontrol at spiroacetalic centres

DOI: 10.1055/s-1992-26317

Source and publish data:

Synthesis p. 1112 - 1118 (1992)

Update date:2022-08-04

Topics:

Authors:

Redlich Redlich

Lenfers Lenfers

Thormahlen

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1992-26317

The new concept for stereocontrol at a spiroacetalic centre in thermodynamically controlled spiroacetalization, based on the operation of the Δ2 effect, allows the synthesis of (-)-Talaromycin A {(3R,4S,6R,9R)-9-ethyl-4-hydroxy-3-hydroxymethyl-1,7-dioxasp

Full text of DOI:10.1055/s-1992-26317

Products guided by the article

Product name:6-O-t-butyldimethylsilyl-1,2-O-isopropylidene-3-O-p-toluenesulfonyl-α-D-glucofuranose

Cas No:146329-36-4

R&D Labs maybe for 146329-36-4

shandong lukang animal & plant drug trading co.,ltd.

Contact:15853765968

Address:floor 9, lukang ,jingying building,#173,taibai building west road,jining city,shandong,china
Shandong Ailitong New Material Co.,Ltd

Contact:+86-536-3226266

Address:zhongjia village, putong town , qingzhou city,Shandong Province,China
Nanjing Chemlin Chemical Co., Ltd.

website:http://www.echemlin.cn

Contact:+86-25-83697070

Address:Rm.902 Longyin Plaza, No. 217 Zhongshan Rd.(N) Nanjing 210009,China
Chemtrade International ( China )

Contact:+86-532-86893005

Address:Rm 2-501, Huaxia Zonghe Building, No. 410 JInggangshan Road, Huangdao
YingYing Pharmaceutical Co.,Ltd

Contact:86-18854126208

Address:55#, yingxiongshan road

Relevant to this article

Substituted 2-azaspiro[5.3]nonan-1-ones as potent cholesterol absorption inhibitors: Defining a binding conformation for SCH 48461

Doi:10.1021/jm00025a002
(1995)
Synthetic Studies toward Pyruvate Acetal Containing Saccharides. Synthesis of the Carbohydrate Part of the Mycobacterium smegmatis Pentasaccharide Glycolipid and Fragments Thereof for the Preparation of Neoantigens

Doi:10.1021/jo00057a021
(1993)
Dimeric building blocks with N-cyanoguanidine linkage for oligonucleotide synthesis

Doi:10.1016/S0040-4039(00)60837-7
(1992)
A NEW GENERAL METHOD OF α-AMIDO-ALKYLATION

Doi:10.1016/S0040-4039(00)88365-3
(1982)
Cross-linked polystyrene-TiCl₄ complex as a reusable Lewis acid catalyst for solvent-free Knoevenagel condensations of 1,3-dicarbonyl compounds with aldehydes

Doi:10.1016/j.catcom.2018.11.001
(2019)
A Novel Synthetic Approach to Pyrrolo<2,3-d>pyrimidine Antifolates

Doi:10.1021/jo00059a016
(1993)

Article Doi