Synthesis of (-)-Talaromycin A. The use of the Δ2 effect for stereocontrol at spiroacetalic centres

DOI: 10.1055/s-1992-26317

Source and publish data:

Synthesis p. 1112 - 1118 (1992)

Update date:2022-08-04

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Authors:

Redlich Redlich

Lenfers Lenfers

Thormahlen

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Article abstract of DOI:10.1055/s-1992-26317

The new concept for stereocontrol at a spiroacetalic centre in thermodynamically controlled spiroacetalization, based on the operation of the Δ2 effect, allows the synthesis of (-)-Talaromycin A {(3R,4S,6R,9R)-9-ethyl-4-hydroxy-3-hydroxymethyl-1,7-dioxasp

Full text of DOI:10.1055/s-1992-26317

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