Synthesis of 2-amino-2-deoxy-D-hexopyranosides from 4-O-trichloroacetimidyl-D-hex-2-enopyranoside by [3,3]-sigmatropic rearrangement

DOI: 10.1016/S0040-4039(00)60858-4

Source and publish data:

Tetrahedron Letters p. 7145 - 7148 (1992)

Update date:2022-07-30

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Authors:

Takeda, Kazuyoshi

Kaji, Eisuke

Konda, Yaeko

Sato, Noriko

Nakamura, Hiroko

Miya, Noriko

Morizane, Aya

Yanagisawa, Yuko

Akiyama, Akira

Zen, Shonosuke

Harigaya, Yoshihiro

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Article abstract of DOI:10.1016/S0040-4039(00)60858-4

2-Amino-2-deoxysugars, D-mannosamine and D-altrosamine derivatives were synthesized together with D-idosamine and D-talosamine ones from a 2-deoxy-2-trichloroacetamido-hex-3-enopyranoside. This key intermediate was prepared by regio- and stereoselective [

Full text of DOI:10.1016/S0040-4039(00)60858-4

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