Synthesis of the C-5 homologue of N-acetylneuraminic acid by enzymatic chain elongation of 2-C-acetamidomethyl-2-deoxy-D-mannose

DOI: 10.1016/S0040-4039(00)74709-5

Source and publish data:

Tetrahedron Letters p. 8031 - 8034 (1992)

Update date:2022-08-04

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Authors:

Koppert, Klaus

Brossmer, Reinhard

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Article abstract of DOI:10.1016/S0040-4039(00)74709-5

Condensation of hexopyranosid-2-ulose 1 with nitromethane afforded after acetylation 2. Treatment with borohydride yielded stereoselectively 4. Reduction, acetylation, deblocking, and acid hydrolysis gave then C-2 branched N-acetylmannosamine 7 that was e

Full text of DOI:10.1016/S0040-4039(00)74709-5

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Product name:Methyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-C-nitromethyl-β-D-mannopyranoside

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