A surprising ring opening mechanism in the formation of α-D-arabinofuranosyl nucleosides from 5-substituted uracils

DOI: 10.1055/s-1992-26363

Source and publish data:

Synthesis p. 1299 - 1306 (1992)

Update date:2022-08-02

Topics:

Authors:

Jorgensen

Pedersen

Nielsen Nielsen

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Article abstract of DOI:10.1055/s-1992-26363

Reaction of silylated 5-substituted uracil derivatives 6 with methyl 2,3,5-tri-O-benzoyl-α-D-arabinofuranoside (3) in the presence of trimethylsilyl trifluoromethanesulfonate afforded a mixture of the corresponding 5-substituted 1-(2,3,5-tri-O-benzoyl-α-D

Full text of DOI:10.1055/s-1992-26363

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