Tetrahedron Letters p. 707 - 710 (1993)
Update date:2022-07-30
Topics:
Rao, A. V. Rama
Bhanu, Manjunath N.
Sharma, G. V. M.
Chiral carbinol 5, made by a titanocene mediated ring opening of epoxy alcohol 11, was converted via an intramolecular radical cyclisation into a 'butanolide template' which was then transformed to the C-12 to C-18 segment 2 of rhizoxin (1). Key Words: Butanolide chiral template; Chiral carbinol; Intramolecular radical cyclisation; Vinyl Grignard reaction.
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