2,6-Diaza-4,8-dicyanosemibullvalene. A short lived intermediate?

DOI: 10.1016/S0040-4039(00)74713-7

Source and publish data:

Tetrahedron Letters p. 8047 - 8050 (1992)

Update date:2022-08-03

Topics:

Authors:

Duell, Bernhard

Muellen, Klaus

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Article abstract of DOI:10.1016/S0040-4039(00)74713-7

Reductive dehalogenation of dichloride 5b with magnesium affords the new stable diazacyclooctatetraene (1,5-diazocine) 7. There is strong evidence for the intermediate formation of a 2, 6-diaza-4,8 - dicyanosemibullvalene 6.

Full text of DOI:10.1016/S0040-4039(00)74713-7

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