Tetrahedron Letters p. 5005 - 5008 (1994)
Update date:2022-08-04
Topics:
Fujio, Mizue
Nomura, Hideyuki
Nakata, Kazuhide
Saeki, Yoshihiro
Mishima, Masaaki
Kobayashi, Shinjiro
Matsushita, Toshio
Nishomoto, Kichisuke
Tsuno, Yuho
The substituent effect on the solvolysis rates of α-t-butyl-α- methylbenzyl chlorides in 80% aq. acetone was correlated to give p=-4.3 and r=0.91 in terms of the LArSR Eq. (1). This slightly reduced r value relative to full conjugation corresponds to a deviation by 0=24.5° from the coplanarity of the benzylic π-system.
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(1992)
