Diastereoselective [2,3] Wittig rearrangement of carbohydrate-derived tertiary allylic ethers. 2. Synthesis of an advanced rapamycin intermediate fromD-glucose

DOI: 10.1016/0040-4039(93)89003-9

Source and publish data:

Tetrahedron Letters p. 753 - 756 (1993)

Update date:2022-08-04

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Authors:

Sin, Ny Sin, Ny

Kallmerten, James

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Article abstract of DOI:10.1016/0040-4039(93)89003-9

The advanced rapamycin intermediate 26 has been prepared by an iterative sigmatropic sequence incorporating the diastereoselective [2,3] Wittig rearrangement of a _D-glucofuranose-derived tertiary allylic ether.

Full text of DOI:10.1016/0040-4039(93)89003-9

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