Diastereoselective [2,3] Wittig rearrangement of carbohydrate-derived tertiary allylic ethers. 2. Synthesis of an advanced rapamycin intermediate fromD-glucose

DOI: 10.1016/0040-4039(93)89003-9

Source and publish data:

Tetrahedron Letters p. 753 - 756 (1993)

Update date:2022-08-04

Topics:

Authors:

Sin, Ny Sin, Ny

Kallmerten, James

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(93)89003-9

The advanced rapamycin intermediate 26 has been prepared by an iterative sigmatropic sequence incorporating the diastereoselective [2,3] Wittig rearrangement of a _D-glucofuranose-derived tertiary allylic ether.

Full text of DOI:10.1016/0040-4039(93)89003-9

Products guided by the article

Product name:(E)-(5S,6R,9R)-5-Benzyloxy-9-((2S,3S,4S,5S)-3-benzyloxy-5-methoxy-4-methyl-tetrahydro-furan-2-yl)-9-methoxymethoxy-6,8-dimethyl-non-7-en-2-yn-4-one

Cas No:147910-31-4

R&D Labs maybe for 147910-31-4

Shandong united-rising pharmaceutical cooperation.,ltd.

Contact:008653187965009

Address:171No., Jing5 Road, Shizhong District, Jinan, China
Shanghai Mintchem Development ., Ltd

Contact:0086 21 5190 8570

Address:R602,4#,89Nong, Mudan Road Pudong Shanghai China
TAIZHOU KEDE CHEMICAL CO., LTD

website:http://www.kedechemical.com

Contact:86-576-84613060 13093829633

Address:Huangyan, Taizhou, Zhejiang,China
JIAXING SUNS INTERNATIONAL TRADE CO LTD

Contact:18367306858

Address:No.123,Huixin Avenue,Huimin Dist
Anhui Sholon New Material Technology Co., Ltd.

website:http://www.sholonchem.com

Contact:+86-550-5261666

Address:4/F Block B, Beijing Chemical Building.No.520 Tianrun Road ,Science & Education Town Wujin District, Changzhou City Jiangsu Province

Relevant to this article

First Asymmetric Synthesis of Enantiopure α-Sulfenyl Dithioacetals and α-Sulfenyl Aldehydes

Doi:10.1021/jo00063a044
(1993)
SYNTHESIS OF THE T <β-D-Gal-(1->3)-α-D-GalNAc>-ANTIGENIC DETERMINANT IN A FORM USEFUL FOR THE PREPARATION OF AN EFFECTIVE ARTIFICAL ANTIGEN AND THE CORRESPONDING IMMUNOADSORBENT

Doi:10.1016/S0008-6215(00)80750-8
(1981)
Nonreductive Desulfenylation of 3-Indolyl Sulfides. Improved Syntheses of 2-Substituted Indoles and 2-Indolyl Sulfides

Doi:10.1021/jo00100a045
(1994)
Europium(II) and ytterbium(II) aryloxide chemistry: Synthesis and crystal structure of [Eu(OC₆H₃Bu₂^t-2,6) ₂(THF)₃]·0.75C₇H₈ and [Yb(OC₆H₃Bu₂

Doi:10.1016/S0277-5387(03)00193-1
(2003)
Ni(I)-Catalyzed Reductive Cyclization of 1,6-Dienes: Mechanism-Controlled trans Selectivity

Doi:10.1016/j.chempr.2017.07.010
(2017)
Convergent Synthesis of 2',3'-Dideoxy-3'-methylthio and 2',3'-Dideoxy-3'-mercapto Nucleosides and their Disulfide Analogues - Potential Anti-HIV Agents

Doi:10.1007/BF00808508
(1993)

Article Doi