Diastereoselective [2,3] Wittig rearrangement of carbohydrate-derived tertiary allylic ethers. 2. Synthesis of an advanced rapamycin intermediate fromD-glucose

DOI: 10.1016/0040-4039(93)89003-9

Source and publish data:

Tetrahedron Letters p. 753 - 756 (1993)

Update date:2022-08-04

Topics:

Authors:

Sin, Ny Sin, Ny

Kallmerten, James

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(93)89003-9

The advanced rapamycin intermediate 26 has been prepared by an iterative sigmatropic sequence incorporating the diastereoselective [2,3] Wittig rearrangement of a _D-glucofuranose-derived tertiary allylic ether.

Full text of DOI:10.1016/0040-4039(93)89003-9

Products guided by the article

Product name:(E)-(5S,6R,9R)-5-Benzyloxy-9-((2S,3S,4S,5S)-3-benzyloxy-5-methoxy-4-methyl-tetrahydro-furan-2-yl)-9-methoxymethoxy-6,8-dimethyl-non-7-en-2-yn-4-one

Cas No:147910-31-4

R&D Labs maybe for 147910-31-4

Anhui Asahikasei Chemical Co., Ltd

Contact:86-551-4259770

Address:No. 88 Linquan Road Hefei Anhui China
CHANGZHOU HANGYU PHARMACEUTICAL TECHNOLOGY CO., LTD

website:http://www.czyys.com

Contact:0086-519-88802789

Address:No.300,Yanling Middle Road, Changzhou, Jiangsu, China
Hangzhou Haichem Co.,Ltd.

Contact:+86-571-86025531 / 86024803

Address:1218-24 Guangyin Mansion,42 Fengqi East Road
Jiangsu Chiatai Qingjiang Pharmaceutical Co.,Ltd

Contact:+86-517-86283327

Address:9 North Hantai Road, Huaian, China
Changzhou BaoKang Pharmaceutical & Chemical Co., Ltd

Contact:(86) 519-88782201 88784080 88785278

Address:Henglin town, changzhou,Jiangsu

Relevant to this article

First Asymmetric Synthesis of Enantiopure α-Sulfenyl Dithioacetals and α-Sulfenyl Aldehydes

Doi:10.1021/jo00063a044
(1993)
SYNTHESIS OF THE T <β-D-Gal-(1->3)-α-D-GalNAc>-ANTIGENIC DETERMINANT IN A FORM USEFUL FOR THE PREPARATION OF AN EFFECTIVE ARTIFICAL ANTIGEN AND THE CORRESPONDING IMMUNOADSORBENT

Doi:10.1016/S0008-6215(00)80750-8
(1981)
Nonreductive Desulfenylation of 3-Indolyl Sulfides. Improved Syntheses of 2-Substituted Indoles and 2-Indolyl Sulfides

Doi:10.1021/jo00100a045
(1994)
Europium(II) and ytterbium(II) aryloxide chemistry: Synthesis and crystal structure of [Eu(OC₆H₃Bu₂^t-2,6) ₂(THF)₃]·0.75C₇H₈ and [Yb(OC₆H₃Bu₂

Doi:10.1016/S0277-5387(03)00193-1
(2003)
Ni(I)-Catalyzed Reductive Cyclization of 1,6-Dienes: Mechanism-Controlled trans Selectivity

Doi:10.1016/j.chempr.2017.07.010
(2017)
Convergent Synthesis of 2',3'-Dideoxy-3'-methylthio and 2',3'-Dideoxy-3'-mercapto Nucleosides and their Disulfide Analogues - Potential Anti-HIV Agents

Doi:10.1007/BF00808508
(1993)

Article Doi