Journal of the Chemical Society, Dalton Transactions p. 959 - 966 (1993)
Update date:2022-08-03
Topics:
Michelin, Rino A.
Bertani, Roberta
Mozzon, Mirto
Bombieri, Gabriella
Benetollo, Franco
Angelici, Robert J.
The reactions of cis- and trans-a = 11.233(2), b = 8.741(2), c = 9.394(2) Angstroem, β = 101.61(3) deg and Z = 2; R = 0. 038 (R'= 0.042) for 2514 measured reflections with l >/= 3?(l).The N-C(R) and (R)C-O bond distances of 1.284(5) and 1.335(5) Angstroem suggest that there is extensive electron delocalization within the N-C(R)-O system.The co-ordination geometry around PtII is planar and the oxazoline rings are only slightly twisted.The formation of Δ2-1,3-oxazolines from platinum(II)-co-ordinated nitriles has also been examined using HOCH2CH2Cl in the presence of the weak base NEt3.These reactions proceed through the initial formation of the bis(imido ester) complexes
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