Chemistry of Heterocyclic Compounds p. 1070 - 1073 (1992)
Update date:2022-07-30
Topics:
Pshenichnyi, G. V.
Mashenkov, V. A.
The corresponding oxazolo<5,4-c>pyridines were obtained in the reaction of stereoisomeric 1-benzyl-3-hydroxy-3-methyl-6-phenyl-4-piperidines with potassium thiocyanate in acetic acid and rearranged into 6-benzyl-5,6,7,8-tetrahydro-1-methyl-3-thioxo-7-phenyloxazolo<3,4-c>pyrimidine by boiling in o-xylene.It was shown that the rearrangement is reversible.
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