International Journal of Chemical Kinetics p. 703 - 718 (1995)
Update date:2022-09-26
Topics:
Antelo, Juan M.
Arce, Florencio
Castro, Maria C.
Crugeiras, Juan
Perez-Moure, Juan C.
Rodriguez, Pilar
The formation of N-chlorobutylamines is a reaction of order one with respect to hypochlorite and amine, and order -1 with respect to OH-.Kinetic studies show that N-chlorobutylamines undergo decomposition in basic aqueous media, and disproportionation (with formation of N,N-dichloramines) in acidic media, mechanisms are put forward for both these processes.
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