Journal of the Chemical Society. Chemical communications p. 846 - 848 (1993)
Update date:2022-08-05
Topics:
Niecke, E.
Nixon, J. F.
Wenderoth, P.
Passos, B. F. Trigo
Nieger, M.
The structure of the first nickel halogeniminophosphine complex, i.e. (PEt3)2Ni(X-P=NAr)2 (Ar = 2,4,6-tri-tert-butylphenyl); X = Cl is reported; reactions of this and related compounds with AlCl3 afford the cationic complexes 7-10; the alkyliminophosphine complexes 12 and 13 are obtained by treatment of the chloroiminophosphine complexes 1a and 4a with Grignard reagent.
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