Vinylidene transition-metal complexes. XXV. Novel square-planar alkynylrhodium anions trans-CR)(PiPr3)2>- as precursors for alkyne, vinylidene and allene rhodium complexes

DOI: 10.1016/0022-328X(93)83024-P

Source and publish data:

Journal of Organometallic Chemistry p. 175 - 182 (1993)

Update date:2022-08-03

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Authors:

Werner, H.

Schneider, D.

Schulz, M.

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Article abstract of DOI:10.1016/0022-328X(93)83024-P

The tetrabutylammonium salts of the novel square-planar alkynylrhodium anions trans-CR)(PⁱPr3)2>^- (R = CO2Et, 4; C6H5, 6) have been prepared by SiMe3 abstraction either from the neutral alkyne or vinylidene complexes, trans

Full text of DOI:10.1016/0022-328X(93)83024-P

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Product name:RhCl(CH₃CCC₆H₅)(P(CH(CH₃)2)3)2

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