Organic and Biomolecular Chemistry p. 6201 - 6204 (2016)
Update date:2022-07-31
Topics:
Chen, Renjie
Qi, Jifeng
Mao, Zhenjun
Cui, Sunliang
A Rh(iii)-catalyzed C-H activation/cyclization of oximes and alkenes for facile and regioselective access to isoquinolines has been developed. This protocol features mild reaction conditions and easily accessible starting materials, and has been applied to the concise synthesis of moxaverine. A kinetic isotope effect study was conducted and a plausible mechanism was proposed.
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Doi:10.1021/ja00353a039
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