Highly Regioselective 7-endo-Aryl Radical Cyclisation: Synthesis of Octahydro-2H-dibenzocycloheptenes

DOI: 10.1039/c39930000809

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 809 - 811 (1993)

Update date:2022-08-03

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Authors:

Ghosh, Ajit K.

Ghosh, Keya

Pal, Sitaram

Chatak, Usha Ranjan

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Article abstract of DOI:10.1039/c39930000809

A highly efficient 7-endo-trig-aryl radical cyclisation of the alkene 6 and the vinylcyclohexanols 11a-d with tri-n-butyltin hydride leading to the respective octahydro-2H-dibenzocycloheptene derivatives 7 and 8 and 12a-d is reported.

Full text of DOI:10.1039/c39930000809

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