Facile Synthesis of (1,2-Dihydrobenzoxazol-2-ylidene)tetracarbonyliron Complexes from 2-Trimethylsiloxyphenyl Isocyanide

DOI: 10.1039/c39930000842

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 842 - 844 (1993)

Update date:2022-09-26

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Authors:

Hahn, F. Ekkehardt

Tamm, Matthias

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Article abstract of DOI:10.1039/c39930000842

Reaction of 2-trimethylsiloxyphenyl isocyanide 3 with Fe(CO)5 and subsequent cleavage of the Si-O bond gives (1,2-dihydrobenzoxazol-2-ylidene)tetracarbonyliron 6, the structure of which has been determined by X-ray crystallography; complex 6 can be alkylated at the ring nitrogen yielding (N-methyl-1,2-dihydrobenzoxazol-2-ylidene)tetracarbonyliron 7.

Full text of DOI:10.1039/c39930000842

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