Journal of the Chemical Society. Chemical communications p. 842 - 844 (1993)
Update date:2022-09-26
Topics:
Hahn, F. Ekkehardt
Tamm, Matthias
Reaction of 2-trimethylsiloxyphenyl isocyanide 3 with Fe(CO)5 and subsequent cleavage of the Si-O bond gives (1,2-dihydrobenzoxazol-2-ylidene)tetracarbonyliron 6, the structure of which has been determined by X-ray crystallography; complex 6 can be alkylated at the ring nitrogen yielding (N-methyl-1,2-dihydrobenzoxazol-2-ylidene)tetracarbonyliron 7.
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