Tetrahedron Letters p. 6845 - 6848 (1993)
Update date:2022-09-26
Topics:
Chen
Wei
Vyas
Doyle
Farina
7,10-Dideoxy taxol 2 was prepared from baccatin III in 4 steps via the Barton deoxygenation reaction. Similarly, 7-epi-10-deoxy taxol 3 was prepared in one step from 7-epi taxol in high yield. The key reaction was the tributyltin hydride-mediated directed reduction of the C10 acetate.
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(2014)Doi:10.1039/P19930002017
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(1993)