Iminophosphorane-mediated one-pot conversion of allyl azides into α-allylated nitriles by a consecutive staudinger reaction/aza-wittig reaction/3-aza-claisen rearrangement process

DOI: 10.1016/0040-4039(91)80623-E

Source and publish data:

Tetrahedron Letters p. 4041 - 4044 (1991)

Update date:2022-08-04

Topics:

Authors:

Molina Molina

Alajarin

Lopez-Leonardo

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Article abstract of DOI:10.1016/0040-4039(91)80623-E

One-pot conversion of allyl azides 1 into nitriles 3 under mild and neutral conditions is reported. The method involves sequential treatment of 1 with triphenylphosphine and the corresponding ketene to give 3.

Full text of DOI:10.1016/0040-4039(91)80623-E

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