THE EFFECT OF ORTHO METHYL GROUPS ON CUMYL SYSTEMS

DOI: 10.1016/S0040-4039(00)92108-7

Source and publish data:

Tetrahedron Letters p. 871 - 874 (1991)

Update date:2022-08-04

Topics:

Authors:

Evilia, Ronald F.

Pan, Dawei

Timberlake, Jack W.

Whittenburg, Scott L.

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Article abstract of DOI:10.1016/S0040-4039(00)92108-7

The reactions of 2-mesityl-2-propanol (2) and 2-mesityl-1-propene (6) have been investigated with the objective of evaluating the effect of ortho methyl groups on chemical reactivity.The 13C NMR spectrum of 2-mesityl-2-propyl cation (3) indicates the expected steric inhibition to resonance.

Full text of DOI:10.1016/S0040-4039(00)92108-7

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