Studies on isocyanides and related compounds: A novel synthetic route to furan derivatives

DOI: 10.1055/s-1993-25940

Source and publish data:

Synthesis p. 783 - 785 (1993)

Update date:2022-08-02

Topics:

Authors:

Bossio Bossio

Marcaccini

Pepino Pepino

Torroba Torroba

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Article abstract of DOI:10.1055/s-1993-25940

The Passerini reaction between arylglyoxals 1, isocyanides 2, and cyanoacetic acid affords N-substituted 3-aryl-2-cyanoacetoxy-3-oxopropionamides 3, which are cyclized in the presence of triethylamine to give N-substituted-3-aryl-4-cyano-2,5-dihydro-5-oxofuran-2-carboxamides 4.

Full text of DOI:10.1055/s-1993-25940

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