Synthetic studies toward the taxane class of natural products

DOI: 10.1016/S0040-4039(00)61711-2

Source and publish data:

Tetrahedron Letters p. 5999 - 6002 (1993)

Update date:2022-08-04

Topics:

Authors:

Kress Kress

Ruel Ruel

Miller Miller

Kishi Kishi

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Article abstract of DOI:10.1016/S0040-4039(00)61711-2

The tricyclic enone 12, containing the taxane ring system, has been synthesized, using an intramolecular Ni(II)/Cr(II)-mediated coupling of β-iodoenone aldehyde 11 as the key step.

Full text of DOI:10.1016/S0040-4039(00)61711-2

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Product name:8-Iodo-3,3,7,7-tetramethyl-1,5-dioxa-spiro[5.5]undec-8-ene

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