A one-pot method for the preparation of (R3P)2Ni0L complexes

DOI: 10.1016/0022-328X(93)80480-Y

Source and publish data:

Journal of Organometallic Chemistry p. 233 - 236 (1993)

Update date:2022-08-03

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Authors:

Stanger, Amnon

Shazar, Anat

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Article abstract of DOI:10.1016/0022-328X(93)80480-Y

A new, general, one-pot method for the preparation of (R3P)2Ni⁰L complexes is described.The method is based on the reductive elimination of (R3P)2NiMe2 in the presence of a free ligand.The elimination can be induced thermally (at r.t. or higher) or photochemically.A comparison between the thermal and photochemical methods was made with several phosphine-nickel complexes.

Full text of DOI:10.1016/0022-328X(93)80480-Y

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