Tetrahedron Letters p. 6611 - 6614 (1993)
Update date:2022-08-05
Topics:
Bailey, Peter L.
Briggs, Andrew D.
Jackson, Richard F. W.
Pietruszka, Joerg
Treatment of enantiomerically pure N-tosylsulfoximinooxiranes 6 with MgBr2 in the presence of tetra-butylammonium borohydride gives enantiomerically enriched bromohydrins 3, together with small amounts of the simple primary alcohols. The bromohydrins are isolated in good yields with enantiomeric excess in the range 70% to 91 % (as assessed by enantioselective g.l.c.
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