STUDIES ON THE TOTAL SYNTHESIS OF LACTACYCLIN. AN IMPROVED ALDOL COUPLING REACTION AND A β-LACTONE INTERMEDIATE IN THIOL ESTER FORMATION

DOI: 10.1016/S0040-4039(00)61575-7

Source and publish data:

Tetrahedron Letters p. 6977 - 6980 (1993)

Update date:2022-08-05

Topics:

Authors:

Corey, E. J.

Reichard, Gregory, A.

Kania, Robert

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Article abstract of DOI:10.1016/S0040-4039(00)61575-7

The recently developed total synthesis of lactacystin (1) has been improved by using the zirconium enolate derived from (R)- or (S)-2-silyloxy-1,2,2-triphenylpropionate which lead stereospecifically to either (6S,7R) or (6R,7S) lactacystin, respectively.T

Full text of DOI:10.1016/S0040-4039(00)61575-7

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