Trigonal-bipyramidal Co-ordinatively Saturated Platinum(II) Olefin Complexes bearing an Organomercury Fragment in Axial Position

DOI: 10.1039/DT9930003421

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3421 - 3426 (1993)

Update date:2022-08-04

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Authors:

Cucciolito, Maria Elena

Giordano, Federico

Panunzi, Achille

Ruffo, Francesco

Felice, Vincenzo De

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Article abstract of DOI:10.1039/DT9930003421

The reactions of organomercury halides HgR'(Cl) (R' = Me, Et, t-Bu or Ph) with complexes of the type >> (dmphen = 2,9-dimethyl-1,10-phenanthroline; R = Me, Et or t-Bu) have been studied.The dmphen ligand with suitable 'in-plane' steric hindrance stabilizes five-co-ordinate adducts of general formula > when R' = alkyl.An influence of the nature of the Hg-bound hydroxyl group on the reaction course is observed.Thus, a cluster containing the Pt-Hg-Pt sequence was obtained when R' = Ph or Cl.The molecular structure of > 1/c; a = 13.079(2), b = 13.167(2), c = 15.495(3) Angstroem and β = 94.18(2) deg> reveals a large trans influence of the organomercury fragment.

Full text of DOI:10.1039/DT9930003421

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