Trigonal-bipyramidal Co-ordinatively Saturated Platinum(II) Olefin Complexes bearing an Organomercury Fragment in Axial Position

DOI: 10.1039/DT9930003421

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3421 - 3426 (1993)

Update date:2022-08-04

Topics:

Authors:

Cucciolito, Maria Elena

Giordano, Federico

Panunzi, Achille

Ruffo, Francesco

Felice, Vincenzo De

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9930003421

The reactions of organomercury halides HgR'(Cl) (R' = Me, Et, t-Bu or Ph) with complexes of the type >> (dmphen = 2,9-dimethyl-1,10-phenanthroline; R = Me, Et or t-Bu) have been studied.The dmphen ligand with suitable 'in-plane' steric hindrance stabilizes five-co-ordinate adducts of general formula > when R' = alkyl.An influence of the nature of the Hg-bound hydroxyl group on the reaction course is observed.Thus, a cluster containing the Pt-Hg-Pt sequence was obtained when R' = Ph or Cl.The molecular structure of > 1/c; a = 13.079(2), b = 13.167(2), c = 15.495(3) Angstroem and β = 94.18(2) deg> reveals a large trans influence of the organomercury fragment.

Full text of DOI:10.1039/DT9930003421

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[Hg(PtCl(2,9-dimethyl-1,10-phenanthroline)(Z-MeO₂CCH=CHCO₂Me))2]

Cas No:153762-33-5

R&D Labs maybe for 153762-33-5

SICHUAN ZHONGBANG NEW MATERIAL CO., LTD

website:http://www.zhongbangst.com

Contact:86-830-2585019

Address:sichuan,china
Beijing Green Guardee Technology CO,.LTD

Contact:+86-10-69706062

Address:F2 BLdj,5 No.37 Chaoqian Road
KangZhiYuan Pharmaceutical Company Limited

Contact:(Sabrina)86-20-85273232

Address:4th floor, building B, Dadi industry zone, Tangxia, Tianhe, Guangzhou, China
Shanghai Longschem Co.,Ltd

Contact:021-36356756

Address:Room601,Building No.14,280 Yangcheng Road,Shanghai
HANGZHOU ZHONGCHANG SCIENTIFIC CO.,LTD

Contact:+86-571-88932183

Address:Hangzhou

Relevant to this article

Photochemical Reaction of 2,3-Di<(E)-styryl>pyrazine Derivatives in the Crystalline State and in Solution

Doi:10.1246/bcsj.66.2987
(1993)
New compounds resulting from structural and biochemical similarities between GBR 1278 and BTCP, two potent inhibitors of dopamine uptake

Doi:10.1016/0223-5234(93)90042-D
(1993)
Mechanism of the 10-methylacridinium ion-sensitized photooxidation of N,N-dibenzylhydroxylamine and its derivatives in acetonitrile

Doi:10.1039/b009206l
(2001)
New succinimides with potent anticancer activity: Synthesis, activation of stress signaling pathways and characterization of apoptosis in leukemia and cervical cancer cells

Doi:10.3390/ijms22094318
(2021)
Novel small molecule guanidine Sigma1 inhibitors for advanced prostate cancer

Doi:10.1016/j.bmcl.2017.03.030
(2017)
Protic ionic liquids and salts as versatile carbon precursors

Doi:10.1021/ja411981c
(2014)

Article Doi