Asymmetric synthesis of (S)-(-)-methyl tropinate: Application of the iron acyl complex (S)-(+)-[(η5-C5H5)Fe(CO)(PPh3) COCH2Ph] as a homochiral phenylacetate enolate equivalent

DOI: 10.1016/S0040-4020(01)87273-2

Source and publish data:

Tetrahedron p. 5635 - 5647 (1993)

Update date:2022-09-26

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Authors:

Baker, Teresa M.

Bodwell, Graham J.

Davies, Stephen G.

Edwards, Alison J.

Metzler, Michael R.

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Article abstract of DOI:10.1016/S0040-4020(01)87273-2

Treatment of the lithium enolate derived from homochiral (S)-[(η⁵-C₅H₅)Fe(CO)(PPh ₃)COCH₃ 5 with benzyne afforded the homochiral phenylacetyl complex (S)-[(η⁵-C₅H₅)Fe(

Full text of DOI:10.1016/S0040-4020(01)87273-2

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