Lewis acid catalyzed geminal acylation reaction of ketones with 1,2-bis((trimethylsilyl)oxy)cyclobutene: Direct formation of 2,2-disubstituted 1,3-cyclopentanediones

DOI: 10.1021/jo00085a041

Source and publish data:

Journal of Organic Chemistry p. 1485 - 1491 (1994)

Update date:2022-09-26

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Authors:

Jenkins Jenkins

Burnell Burnell

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Article abstract of DOI:10.1021/jo00085a041

Ketones reacted with 1,2-bis((trimethylsilyl)oxy)cyclobutene (1) under catalysis by boron trifluoride etherate to yield 2,2-disubstituted 1,3-cyclopentanedione products via silylated cyclobutanone intermediates in a two-step, one-pot process. In many inst

Full text of DOI:10.1021/jo00085a041

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