Chlormethylchlorphosphane R(Cl)P-CH2-Cl-Synthone fuer den Aufbau von Phosphaalkenen im Metalltemplat

Article abstract of DOI:10.1016/0022-328X(93)83348-Y

On reaction of the chloromethylchlorophosphines R(Cl)P-CH2-Cl (R=Cl, i-Pr, t-Bu, NEt2, N(i-Pr)2, NPh2, O-2,6-i-Pr2C6H3; 1-7) with diiron enneacarbonyl the iron carbonyl complexes 8-14 are formed in good yields.Dehalogenation of the phosphine complexes 9-1