Tetrahedron p. 285 - 304 (1994)
Update date:2022-09-26
Topics:
Larhed, Mats
Andersson, Carl-Magnus
Hallberg, Anders
Palladium-catalyzed arylation reactions of <2-(Dimethylamino)ethoxy>ethene (1) with a series of aryl triflates were performed under a variety of reaction conditions.In particular, the influence of phosphine ligands and halide additives on regioselectivity were studied.It was found that the chelation-controlled arylation of 1 affords an expedient route for the conversion of phenols into arylacetaldehydes.Alternatively, the same starting materials could be used to synthesize acetophenones by reversing the regioselectivity with bidentate phosphine ligands.
View MoreWEIFANG DERUN CHEMICAL CO.,LTD
Contact:86-536-8956886
Address:weifang
Contact:+86-0592 5353131
Address:No.56 Guani Road Software Park 2,Siming District
NANCHANG QINZHI SCI&TEC.CO.,LTD(expird)
Contact:+86-13687004106
Address:Hero South Road,Hero Zone,Nanchang,Jiangxi,China
Ningbo Hi-tech Zone Nice-Synth Chemical Industry Ltd.
Contact:+86-(574)-81110986
Address:No. 1210, Building 3, Wante Business Centre, Hi-tech Zone, Ningbo
JiangXi Hong Run Chemical Co., Ltd
Contact:+86-0791-88521351
Address:XingHuo industrial zone in YongXiu county
Doi:10.1016/j.tet.2013.12.073
(2014)Doi:10.3390/molecules181113654
(2013)Doi:10.1021/cg4013608
(2014)Doi:10.1016/S0040-4039(00)61419-3
(1993)Doi:10.1246/cl.1994.157
(1994)Doi:10.1007/BF00780402
(1993)