An Unusual Rearrangement of a Lithiated N-Acyl-tetrahydroisoquinoline to an Amino-indan Skeleton and Structural Comparison of 3-Amino-2-methylindan- and -tetrahydronaphthalene-2-carboxylic Acids as Possible Building Blocks for Peptide-Turn Mimics

DOI: 10.1002/hlca.19930760721

Source and publish data:

Helvetica Chimica Acta p. 2640 - 2653 (1993)

Update date:2022-07-31

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Authors:

Gees, Thomas

Schweizer, W. Bernd

Seebach, Dieter

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Article abstract of DOI:10.1002/hlca.19930760721

Lithium 1-lithio-6,7-dimethoxy-3-methyl-2-pivaloyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylate rearranges to the dilithio derivative of 5,6-dimethoxy-2-methyl-1-(pivaloylamino)indan-2-carboxylic acid (2, <1,2>-sigmatropic shift with retention of configur

Full text of DOI:10.1002/hlca.19930760721

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