Synthesis of ring B-rearranged taxane analogs

DOI: 10.1021/jo00088a017

Source and publish data:

Journal of Organic Chemistry p. 2370 - 2373 (1994)

Update date:2022-07-31

Topics:

Authors:

Klein Klein

Maring Maring

Yeung Yeung

Thomas Thomas

Grampovnik

Plattner

Henry Henry

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Article abstract of DOI:10.1021/jo00088a017

Reaction of the C-7 hydroxyl group on the 9-dihydrotaxane skeleton with triflic anhydride causes a major skeletal rearrangement to occur leading to contraction of ring B. In addition the formation of a ring C-fused cyclopropane structure occurs. The requi

Full text of DOI:10.1021/jo00088a017

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