Ring enlargement of phosphatriafulvenes with azides to 1H-2-iminophosphetes

DOI: 10.1016/S0040-4039(00)76749-9

Source and publish data:

Tetrahedron Letters p. 1527 - 1530 (1994)

Update date:2022-08-04

Topics:

Authors:

Eisfeld, Wolfgang

Slany, Michael

Bergstraesser, Uwe

Regitz, Manfred

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Article abstract of DOI:10.1016/S0040-4039(00)76749-9

The reaction of the mesitylphosphatriafulvene 2 with the azides 3a-k yields the ring-enlarged 1H-2-iminophosphetes 6a-k; the structure of 6j was irrevocably established by an X-ray crystal structure analysis. In some cases, 1,3-diphosphetanes (8b-e) have been characterized as by-products.

Full text of DOI:10.1016/S0040-4039(00)76749-9

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