Tandem Radical Cycloaddition. Remarkable Silyl Substituent Effect on the Chemoselectivity of the Radical Cyclization Reactions

DOI: 10.1021/jo00073a002

Source and publish data:

Journal of Organic Chemistry p. 5574 - 5575 (1993)

Update date:2022-08-04

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Authors:

Weng, Wu-Wang

Luh, Tien-Yau

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Article abstract of DOI:10.1021/jo00073a002

Tandem radical cyclization of bromides 1 with Bu3SnH is extremely sensitive to the nature of the substituent on the diene moiety.Bicyclo<3.1.0> skeleton 3 is obtained in the presence of the silyl substituent.The tert-butyl substituent gives exclusively si

Full text of DOI:10.1021/jo00073a002

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