Carbon-Tellurium Bond Cleavage in Tellurolatochromium Complexes. Synthesis and Single-crystal Structures of (cp = η5-C5H5, n = 1-3)

DOI: 10.1039/DT9940002697

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2697 - 2704 (1994)

Update date:2022-08-04

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Authors:

Goh, Lai Yoong

Chen, Wei

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Article abstract of DOI:10.1039/DT9940002697

The exhaustive thermolysis of (cp = η⁵-C5H5) in toluene for 48 h at 80 deg C led to the isolation of (ca. 24percent), (14.4percent), (37.2percent) and in minute amounts.Thin-layer chromatography and proton NMR spectral monitoring showed the formation of and from the intermediate <2Te>.Under thermolytic conditions, and undergo reversible transformation with simultaneous formation of .The structures of three of the complexes were established by X-ray diffraction analysis.

Full text of DOI:10.1039/DT9940002697

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